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In diffusion and electronic energy structure in polymer layers on In tin oxide

Identifieur interne : 002C62 ( Main/Repository ); précédent : 002C61; suivant : 002C63

In diffusion and electronic energy structure in polymer layers on In tin oxide

Auteurs : RBID : Pascal:11-0218544

Descripteurs français

Pascal (Inist)
- Diffusion(transport), Structure électronique, Structure polymère, Spectrométrie photoélectron, Orbitale moléculaire, Polymère, Surcouche, Butyrique dérivé polymère, Analyse numérique, Profil raie, Niveau coeur, Soufre, Spectre photoélectron RX, Oxyde d'étain, Thiophène dérivé polymère, Oxyde d'indium, Substrat polymère, S, 6835F, 7320, 7320A.
Wicri :
- concept : Polymère, Soufre.

English descriptors

KwdEn :
- Butyric derivative polymer, Core levels, Diffusion, Electronic structure, Indium oxide, Line shape, Molecular orbital, Numerical analysis, Overlayers, Photoelectron spectroscopy, Polymer structure, Polymers, Sulfur, Thiophene derivative polymer, Tin oxide, X-ray photoelectron spectra.

Abstract

We have investigated the effect of In diffusion on the electronic structure of a polyethylenedioxythiophene-poly (styrenesulfonate) layer deposited on InSn_xO₁ _{- x} substrate by photoelectron spectroscopy. We observe additional states near the highest occupied molecular orbital of the polymer layer that are generated by In releases from the substrate. Also, we observe that In diffusion continues into an overlayer of a mixture of poly (3-hexylthiophene) and [6,6]-phenyl C61-butyric acid methyl ester. On the basis of the results of the numerical line shape analysis of In 3d_5/2 core level emission, we rule out the presence of metallic In clusters within the organic layers and suggest instead that In/sulfur compounds are present within the organic layers.

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Pascal:11-0218544

Le document en format XML

<record><TEI><teiHeader><fileDesc><titleStmt><title xml:lang="en" level="a">In diffusion and electronic energy structure in polymer layers on In tin oxide</title>
<author><name sortKey="Skraba, Polona" uniqKey="Skraba P">Polona Skraba</name>
<affiliation wicri:level="1"><inist:fA14 i1="01"><s1>University of Nova Gorica, Laboratory for Organic Matter Physics, Vipavska 13</s1>
<s2>5000 Nova Gorica</s2>
<s3>SVN</s3>
<sZ>1 aut.</sZ>
<sZ>2 aut.</sZ>
</inist:fA14>
<country>Slovénie</country>
<wicri:noRegion>5000 Nova Gorica</wicri:noRegion>
</affiliation>
</author>
<author><name sortKey="Bratina, Gvido" uniqKey="Bratina G">Gvido Bratina</name>
<affiliation wicri:level="1"><inist:fA14 i1="01"><s1>University of Nova Gorica, Laboratory for Organic Matter Physics, Vipavska 13</s1>
<s2>5000 Nova Gorica</s2>
<s3>SVN</s3>
<sZ>1 aut.</sZ>
<sZ>2 aut.</sZ>
</inist:fA14>
<country>Slovénie</country>
<wicri:noRegion>5000 Nova Gorica</wicri:noRegion>
</affiliation>
</author>
<author><name sortKey="Igarashi, Satoru" uniqKey="Igarashi S">Satoru Igarashi</name>
<affiliation wicri:level="1"><inist:fA14 i1="02"><s1>Tokyo City University, 1-28-1 Tamazutsumi</s1>
<s2>Setagaya, Tokyo 158-8557</s2>
<s3>JPN</s3>
<sZ>3 aut.</sZ>
<sZ>4 aut.</sZ>
</inist:fA14>
<country>Japon</country>
<wicri:noRegion>Setagaya, Tokyo 158-8557</wicri:noRegion>
</affiliation>
</author>
<author><name sortKey="Nohira, Hirosi" uniqKey="Nohira H">Hirosi Nohira</name>
<affiliation wicri:level="1"><inist:fA14 i1="02"><s1>Tokyo City University, 1-28-1 Tamazutsumi</s1>
<s2>Setagaya, Tokyo 158-8557</s2>
<s3>JPN</s3>
<sZ>3 aut.</sZ>
<sZ>4 aut.</sZ>
</inist:fA14>
<country>Japon</country>
<wicri:noRegion>Setagaya, Tokyo 158-8557</wicri:noRegion>
</affiliation>
</author>
<author><name sortKey="Hirose, Kazuyuki" uniqKey="Hirose K">Kazuyuki Hirose</name>
<affiliation wicri:level="1"><inist:fA14 i1="03"><s1>Institute of Space and Astronautical Science, 3-1-1 Yoshinodai</s1>
<s2>Sagamihara, Kanagawa 252-5210</s2>
<s3>JPN</s3>
<sZ>5 aut.</sZ>
</inist:fA14>
<country>Japon</country>
<wicri:noRegion>Sagamihara, Kanagawa 252-5210</wicri:noRegion>
</affiliation>
</author>
</titleStmt>
<publicationStmt><idno type="inist">11-0218544</idno>
<date when="2011">2011</date>
<idno type="stanalyst">PASCAL 11-0218544 INIST</idno>
<idno type="RBID">Pascal:11-0218544</idno>
<idno type="wicri:Area/Main/Corpus">003221</idno>
<idno type="wicri:Area/Main/Repository">002C62</idno>
</publicationStmt>
<seriesStmt><idno type="ISSN">0040-6090</idno>
<title level="j" type="abbreviated">Thin solid films</title>
<title level="j" type="main">Thin solid films</title>
</seriesStmt>
</fileDesc>
<profileDesc><textClass><keywords scheme="KwdEn" xml:lang="en"><term>Butyric derivative polymer</term>
<term>Core levels</term>
<term>Diffusion</term>
<term>Electronic structure</term>
<term>Indium oxide</term>
<term>Line shape</term>
<term>Molecular orbital</term>
<term>Numerical analysis</term>
<term>Overlayers</term>
<term>Photoelectron spectroscopy</term>
<term>Polymer structure</term>
<term>Polymers</term>
<term>Sulfur</term>
<term>Thiophene derivative polymer</term>
<term>Tin oxide</term>
<term>X-ray photoelectron spectra</term>
</keywords>
<keywords scheme="Pascal" xml:lang="fr"><term>Diffusion(transport)</term>
<term>Structure électronique</term>
<term>Structure polymère</term>
<term>Spectrométrie photoélectron</term>
<term>Orbitale moléculaire</term>
<term>Polymère</term>
<term>Surcouche</term>
<term>Butyrique dérivé polymère</term>
<term>Analyse numérique</term>
<term>Profil raie</term>
<term>Niveau coeur</term>
<term>Soufre</term>
<term>Spectre photoélectron RX</term>
<term>Oxyde d'étain</term>
<term>Thiophène dérivé polymère</term>
<term>Oxyde d'indium</term>
<term>Substrat polymère</term>
<term>S</term>
<term>6835F</term>
<term>7320</term>
<term>7320A</term>
</keywords>
<keywords scheme="Wicri" type="concept" xml:lang="fr"><term>Polymère</term>
<term>Soufre</term>
</keywords>
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<front><div type="abstract" xml:lang="en">We have investigated the effect of In diffusion on the electronic structure of a polyethylenedioxythiophene-poly (styrenesulfonate) layer deposited on InSn<sub>x</sub>
O<sub>1</sub>
 <sub>- x</sub>
 substrate by photoelectron spectroscopy. We observe additional states near the highest occupied molecular orbital of the polymer layer that are generated by In releases from the substrate. Also, we observe that In diffusion continues into an overlayer of a mixture of poly (3-hexylthiophene) and [6,6]-phenyl C61-butyric acid methyl ester. On the basis of the results of the numerical line shape analysis of In 3d<sub>5/2</sub>
 core level emission, we rule out the presence of metallic In clusters within the organic layers and suggest instead that In/sulfur compounds are present within the organic layers.</div>
</front>
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<fA08 i1="01" i2="1" l="ENG"><s1>In diffusion and electronic energy structure in polymer layers on In tin oxide</s1>
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<fA11 i1="01" i2="1"><s1>SKRABA (Polona)</s1>
</fA11>
<fA11 i1="02" i2="1"><s1>BRATINA (Gvido)</s1>
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<fA11 i1="03" i2="1"><s1>IGARASHI (Satoru)</s1>
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<fA11 i1="04" i2="1"><s1>NOHIRA (Hirosi)</s1>
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<fA11 i1="05" i2="1"><s1>HIROSE (Kazuyuki)</s1>
</fA11>
<fA14 i1="01"><s1>University of Nova Gorica, Laboratory for Organic Matter Physics, Vipavska 13</s1>
<s2>5000 Nova Gorica</s2>
<s3>SVN</s3>
<sZ>1 aut.</sZ>
<sZ>2 aut.</sZ>
</fA14>
<fA14 i1="02"><s1>Tokyo City University, 1-28-1 Tamazutsumi</s1>
<s2>Setagaya, Tokyo 158-8557</s2>
<s3>JPN</s3>
<sZ>3 aut.</sZ>
<sZ>4 aut.</sZ>
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<fA14 i1="03"><s1>Institute of Space and Astronautical Science, 3-1-1 Yoshinodai</s1>
<s2>Sagamihara, Kanagawa 252-5210</s2>
<s3>JPN</s3>
<sZ>5 aut.</sZ>
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<fA20><s1>4216-4219</s1>
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<fA21><s1>2011</s1>
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<fA23 i1="01"><s0>ENG</s0>
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<fA43 i1="01"><s1>INIST</s1>
<s2>13597</s2>
<s5>354000192974990160</s5>
</fA43>
<fA44><s0>0000</s0>
<s1>© 2011 INIST-CNRS. All rights reserved.</s1>
</fA44>
<fA45><s0>24 ref.</s0>
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<fA47 i1="01" i2="1"><s0>11-0218544</s0>
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<fA60><s1>P</s1>
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<fA61><s0>A</s0>
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<fA66 i1="01"><s0>NLD</s0>
</fA66>
<fC01 i1="01" l="ENG"><s0>We have investigated the effect of In diffusion on the electronic structure of a polyethylenedioxythiophene-poly (styrenesulfonate) layer deposited on InSn<sub>x</sub>
O<sub>1</sub>
 <sub>- x</sub>
 substrate by photoelectron spectroscopy. We observe additional states near the highest occupied molecular orbital of the polymer layer that are generated by In releases from the substrate. Also, we observe that In diffusion continues into an overlayer of a mixture of poly (3-hexylthiophene) and [6,6]-phenyl C61-butyric acid methyl ester. On the basis of the results of the numerical line shape analysis of In 3d<sub>5/2</sub>
 core level emission, we rule out the presence of metallic In clusters within the organic layers and suggest instead that In/sulfur compounds are present within the organic layers.</s0>
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<fC02 i1="02" i2="3"><s0>001B70C20A</s0>
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<fC03 i1="01" i2="3" l="FRE"><s0>Diffusion(transport)</s0>
<s5>01</s5>
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<fC03 i1="01" i2="3" l="ENG"><s0>Diffusion</s0>
<s5>01</s5>
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<fC03 i1="02" i2="3" l="FRE"><s0>Structure électronique</s0>
<s5>02</s5>
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<fC03 i1="02" i2="3" l="ENG"><s0>Electronic structure</s0>
<s5>02</s5>
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<fC03 i1="03" i2="3" l="FRE"><s0>Structure polymère</s0>
<s5>03</s5>
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<fC03 i1="03" i2="3" l="ENG"><s0>Polymer structure</s0>
<s5>03</s5>
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<fC03 i1="04" i2="3" l="FRE"><s0>Spectrométrie photoélectron</s0>
<s5>04</s5>
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<fC03 i1="04" i2="3" l="ENG"><s0>Photoelectron spectroscopy</s0>
<s5>04</s5>
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<s5>05</s5>
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<s5>05</s5>
</fC03>
<fC03 i1="05" i2="X" l="SPA"><s0>Orbital molecular</s0>
<s5>05</s5>
</fC03>
<fC03 i1="06" i2="3" l="FRE"><s0>Polymère</s0>
<s5>06</s5>
</fC03>
<fC03 i1="06" i2="3" l="ENG"><s0>Polymers</s0>
<s5>06</s5>
</fC03>
<fC03 i1="07" i2="3" l="FRE"><s0>Surcouche</s0>
<s5>07</s5>
</fC03>
<fC03 i1="07" i2="3" l="ENG"><s0>Overlayers</s0>
<s5>07</s5>
</fC03>
<fC03 i1="08" i2="X" l="FRE"><s0>Butyrique dérivé polymère</s0>
<s2>NK</s2>
<s5>08</s5>
</fC03>
<fC03 i1="08" i2="X" l="ENG"><s0>Butyric derivative polymer</s0>
<s2>NK</s2>
<s5>08</s5>
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<fC03 i1="08" i2="X" l="SPA"><s0>Butírico derivado polímero</s0>
<s2>NK</s2>
<s5>08</s5>
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<s5>09</s5>
</fC03>
<fC03 i1="09" i2="3" l="ENG"><s0>Numerical analysis</s0>
<s5>09</s5>
</fC03>
<fC03 i1="10" i2="3" l="FRE"><s0>Profil raie</s0>
<s5>10</s5>
</fC03>
<fC03 i1="10" i2="3" l="ENG"><s0>Line shape</s0>
<s5>10</s5>
</fC03>
<fC03 i1="11" i2="3" l="FRE"><s0>Niveau coeur</s0>
<s5>11</s5>
</fC03>
<fC03 i1="11" i2="3" l="ENG"><s0>Core levels</s0>
<s5>11</s5>
</fC03>
<fC03 i1="12" i2="3" l="FRE"><s0>Soufre</s0>
<s2>NC</s2>
<s5>12</s5>
</fC03>
<fC03 i1="12" i2="3" l="ENG"><s0>Sulfur</s0>
<s2>NC</s2>
<s5>12</s5>
</fC03>
<fC03 i1="13" i2="3" l="FRE"><s0>Spectre photoélectron RX</s0>
<s5>13</s5>
</fC03>
<fC03 i1="13" i2="3" l="ENG"><s0>X-ray photoelectron spectra</s0>
<s5>13</s5>
</fC03>
<fC03 i1="14" i2="X" l="FRE"><s0>Oxyde d'étain</s0>
<s5>15</s5>
</fC03>
<fC03 i1="14" i2="X" l="ENG"><s0>Tin oxide</s0>
<s5>15</s5>
</fC03>
<fC03 i1="14" i2="X" l="SPA"><s0>Estaño óxido</s0>
<s5>15</s5>
</fC03>
<fC03 i1="15" i2="X" l="FRE"><s0>Thiophène dérivé polymère</s0>
<s2>NK</s2>
<s5>16</s5>
</fC03>
<fC03 i1="15" i2="X" l="ENG"><s0>Thiophene derivative polymer</s0>
<s2>NK</s2>
<s5>16</s5>
</fC03>
<fC03 i1="15" i2="X" l="SPA"><s0>Tiofeno derivado polímero</s0>
<s2>NK</s2>
<s5>16</s5>
</fC03>
<fC03 i1="16" i2="X" l="FRE"><s0>Oxyde d'indium</s0>
<s5>17</s5>
</fC03>
<fC03 i1="16" i2="X" l="ENG"><s0>Indium oxide</s0>
<s5>17</s5>
</fC03>
<fC03 i1="16" i2="X" l="SPA"><s0>Indio óxido</s0>
<s5>17</s5>
</fC03>
<fC03 i1="17" i2="3" l="FRE"><s0>Substrat polymère</s0>
<s4>INC</s4>
<s5>46</s5>
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<fC03 i1="18" i2="3" l="FRE"><s0>S</s0>
<s4>INC</s4>
<s5>47</s5>
</fC03>
<fC03 i1="19" i2="3" l="FRE"><s0>6835F</s0>
<s4>INC</s4>
<s5>71</s5>
</fC03>
<fC03 i1="20" i2="3" l="FRE"><s0>7320</s0>
<s4>INC</s4>
<s5>72</s5>
</fC03>
<fC03 i1="21" i2="3" l="FRE"><s0>7320A</s0>
<s4>INC</s4>
<s5>73</s5>
</fC03>
<fN21><s1>143</s1>
</fN21>
<fN44 i1="01"><s1>OTO</s1>
</fN44>
<fN82><s1>OTO</s1>
</fN82>
</pA>
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In diffusion and electronic energy structure in polymer layers on In tin oxide

In diffusion and electronic energy structure in polymer layers on In tin oxide

Descripteurs français

English descriptors

Abstract

Links toward previous steps (curation, corpus...)

Links to Exploration step

Le document en format XML

Pour manipuler ce document sous Unix (Dilib)

Pour mettre un lien sur cette page dans le réseau Wicri